[内容简介]
This book includes advanced materials and nanocomposites based on silica and layered silicates. Obtained from resources in China. Using nanotechnology, these inorganic materials can be filled, in-situ polymerised and combined with polymers with nanoscale
[目次]

Contents: Preface

Chapter

1  The general background of polymer-silicate and silica nanocomposites

Introduction

1.1   Layered silicates

1.1.1          Nanostructurein nature

1.1.2          Classifications of silicates

1.1.3          Layerstructure of silicates

1.1.4          Natural mineral resourses of silicates in China

1.1.5          The world minerals for silicates

1.2   Silica

1.2.1          Precursor of silica

1.2.2          Resources

1.2.3          Monodisperse silica

1.3   Physical properties of layered silicates and silica

1.3.1Condensed structure

1.3.2 Particle and porosity

1.3.3Double electric layer

1.3.4 Zeta potential

1.3.5Flocculation and coagulation

1.3.6 Gel properties

1.4   Polymers and Polymerizations

1.4.1 Multiple structure of polymers

1.4.2 Polymers for Nanocomposites

1.4.3 In-situ polymerization composites

1.5   Preparation and technology for Nanocomposites

1.5.1          Brief introduction of nanocomposite preparation

1.5.2          General design and aspects for nanocomposite

1.5.3          Technology for nanocomposites

1.5.4          Intercalation chemistry for nanocomposites

1.5.5 Nanocomposites by sol-gel process

1.6 The new phenomena in polymer-silicate and silica nanocomposites

1.6   Prospect References Chapter

2         The silicate and silica modification Introduction

2.1   Silicate modifications

2.1.1 Silicate purifying  

2.1.2 Surface treatment

2.1.3 Absorption and intercalation

2.2 Silica modification

2.2.1 Particle grade for polymerization

2.2.2 Silica modification

2.2.3 Monodispersed silica modification

2.3 Melt intercalation

2.3.1 Precursor preparation

2.3.2 Melting techniques

2.4 Intercalation in solvent or mixed solution

2.4.1 Solvent intercalation

2.4.2 Preparation of emulsions

2.4.3 Intercalation reaction in emulsions

2.5 Modification particles for Polymerization

2.5.1 Design of polymerization reaction

2.5.2 Monomer Intercalation

2.5.3 Oligomer-silica mixtures

2.5.4 Oligomer-silica mixtures

2.5.5 In-situ Polymerization in media

2.5.6 Polymerization by adding modified particles

2.5.7 Polymerization with oligomer-particle mixtures References Chapter

3         Polymer-inorganic layered silicate and silica nanocomposites Introduction

3.1 PA-silicate nanocomposites

3.1.1 PA6,PA66 and PA11

3.1.2 Preparations

3.1.3 Properties

3.1.4 Products

3.2 PEO-silicate nanocomposites

3.2.1 Oligomer and polymers of ethylene oxide

3.2.2 Preparations

3.2.2 Properties

3.2.3 Products

3.3 Polyolefin-silicate nanocomposite

3.3.1 PP,PE and PS

3.3.2 Preparations

3.3.3 Properties

3.3.4 Products

3.4 Polyester-silicate nanocomposite

3.4.1 PET and PBT

3.4.2 Preparations

3.4.3 Properties

3.4.4 Products

3.5 Polyaniline-silicate nanocomposites

3.5.1 PAN and its conductivity

3.5.2 Preparation and polymerization

3.3.3 Functional properties

3.3.4 Nano effect in PAN ?LS nanocompsites

3.3.5 Design polymers with new functions

3.6 Other kinds of Polymer-silicate nanocomposites

3.6.1 Polyolefin oligomer based nanocomposites

3.6.2 Polyimides based nanocomposites

3.6.3 Polyacrylated amine based nanocomposites

3.6.4 Copolymer based nanocomposites

3.7 Silica-Polymer nanocomposites

3.7.1 Assemble and self-assemble

3.7.2 Particle arrays

3.7.3 Properties and products References Chapter

4 Morphology, Assemble and Properties

Introduction

4.1 Nanostructure and morphology

4.1.1  Particle statistical distribution

4.1.2  Particle size deviation

4.1.3  Phase separation

4.1.4  Particle order

4.1.5  Agglomerations

4.1.6  Intercalation Dynamics

4.1.7  Particle distribution morphology-property relationship

4.2  Crystallization

4.2.1 Recrystallization

4.2.2  Isothermal or nonisothermal crystallization

4.2.3  Phase transformation

4.2.4  Crystallization degree and rate

4.2.5  Polymorphism in crystallization

4.2.6  Crystallization morphology - property relationship

4.3 Thermal properties

4.3.1  Melting behavior

4.3.2  HDT

4.3.3  Thermal degradation

4.3.4  Specific Heat

4.3.5 Particle load - property relationship

4.4 Mechanical properties

4.4.1 Tensile and bending

4.4.2 brittle ductile

4.4.3 Modulus

4.4.4 Particle load- mechanical property relationship

4.5  Special properties by assemble of nanocomposites

4.5.1 Assemble and self-assemble

4.5.2 Opals and Inverse Opals

4.5.3 Optical Properties

4.5.4 Electric Properties

4.5.5 Nucleation and Magnetic properties

4.5.6 Liquid crystal behavior

4.5.7 Double melting behavior

4.6 Functional properties by nanoparticle assemble

4.6.1 Transparency

4.6.2 Barrier properties

4.6.3 Oxidation-resistance

4.6.4 UV-resistance

4.6.5 Reflect properties

4.7 Rheology of nanocomposites

4.8 Nucleation and Order

4.8.1 The nucleation principle

4.8.2 Nucleation in polymer-clay nanocomposites

4.8.3 Nucleation of polymer surfactant-metal nanoparticles

4.8.4 Nucleation of silica in nanocomposites

4.8.5 Nucleation in solution, melt and annealing References Chapter

5 Characterization and techniques Introduction

5.1 Particle

5.1.1 Porous structure

5.1.2 Property of Surface

5.1.3 Particle distribution

5.1.4 Particles measuring and statistics

5.2 Properties

5.2.1 Halpin-Tsai equations

5.2.2 Mechanical properties

5.2.3 Thermal properties

5.2.4 Barrier Properties

5.2.5 Other functional properties

5.3 Techniques for Structure Characterization

5.3.1 AFM

5.3.2 TEM

5.3.3 X-ray

5.3.4 SAXS

5.3.5 Computer modelling

5.4 Techniques for Structure ?property Characterization

5.4.1 SEM

5.4.2 PLM

5.4.3 DSC References Chapter

6 The applications and products Introduction

6.1 The applications

6.1.1 Barrier materials

6.1.2 Fire-retardent materials

6.1.3 Engineering plastics

6.1.4 Clothes

6.1.5 Packages

6.1.6 Coatings

6.1.7 Electronics

6.1.8 Catalysts

6.1.9 Carriers

6.1.10 Additives

6.2 Products

6.2.1 Products in industry

6.2.2 Products quality control

6.2.3 Products markets

6.3 Nanocomposites and traditional industry

6.3.1 Chemical industry and engineering

6.3.2 Construction

6.3.3 Reformation of traditional industry

6.4 Prospect References