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Molecular clusters : a bridge to solid-state chemistry (分子簇: 固态化学的桥梁)
发布日期:2008-05-28  浏览

Description:

Clusters can be viewed as solids at the nano-scale, yet molecular cluster chemistry and solid state chemistry have traditionally been considered as separate topics. This treatment has made it conceptually difficult to appreciate commonalities of structure and bonding between the two. Using analogous models, this is the first book to form a connecting bridge. Although the focus is on clusters, sufficient attention is paid to solid-state compounds at each stage of the development to establish the interrelationship between the two topics. Comprehensive coverage of cluster types by composition, size and ligation, is provided, as is a synopsis of selected research. Written in an accessible style and highly illustrated to aid understanding, this book is suitable for researchers in inorganic chemistry, physical chemistry, materials science, and condensed matter physics.
Table of Contents:

1 Introduction 1
2 Main-group clusters : geometric and electronic structure 33
3 Transition-metal clusters : geometric and electronic structure 85
4 Isolobal relationships between main-group and transition-metal fragments : connections to organometallic chemistry 139
5 Main-group-transition-metal clusters 165
6 Transition to the solid state 205
7 From molecules to extended solids 257
8 Inter-conversion of clusters and solid-state materials 303
App Fundamental concepts : a concise review 323

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