【内容简介】
This is the second time that we have prepared a new edition of Vogel's Textbook of Organic Chemistry and it is important to reaffirm the aims set out by the late Dr A. I. Vogel in the preface to the first edition. Thus in this new edition every endeavour is made to retain the comprehensive character of the book, and to ensure that it continues to be a one-volume reference text which is of value to practising organic chemists throughout their undergraduate, postgraduate and subsequent careers. ...
?目录

CHAPTER 1 ORGANIC SYNTHESIS

1.1 INTRODUCTION

1.2 STRUCTURE OF THE TARGET MOLECULE

1.3 REACTION MECHANISM AND THE METHODOLOGY OF SYNTHESIS

1.4 REACTION MECHANISM AND THE STRATEGY OF SYNTHESIS

1.5 CONCLUSION

CHAPTER 2 EXPERIMENTAL TECHNIOUES

2.1    GENERAL INSTRUCTIONS FOR SAFE WORKING IN ORGANIC CHEMICAL LABORATORIES

2.2    PLANNING OF EXPERIMENTS AND RECORDING OF RESULTS

2.3    HAZARDS IN ORGANIC CHEMISTRY LABORATORIES

2.4    INTERCHANGEABLE GROUND GLASS JOINTS

2.5    TYPES OF GROUND GLASS JOINTS

2.6    CARE AND MAINTENANCE OF GROUND GLASS JOINTS

2.7    APPARATUS WITH INTERCHANGEABLE GROUND GLASS JOINTS SUITABLE FOR GENERAL USE IN PREPARATIVE ORGANIC CHEMISTRY

2.8    OTHER TYPES OF INTERCHANGEABLE JOINTS AND STOPCOCKS

2.9              THE USE OF CORKS AND RUBBER STOPPERS

2.10          CUTTING AND BENDING OF GLASS TUBING

2.11          GENERAL LABORATORY APPARATUS

2.12          COOLING OF REACTION MIXTURES

2.13          HEATING OF REACTION MIXTURES

2.14          MECHANICAL AGITATION

2.15          TYPICAL GROUND GLASS JOINT ASSEMBLIES FOR STANDARD REACTION PROCEDURES

2.16          PRECAUTIONS FOR UNATTENDED REACTIONS

2.17          APPARATUS FOR SPECIAL REACTION TECHNIQUES

2.18          GENERAL CONSIDERATIONS

2.19          FILTRATION TECHNIQUES

2.20          RECRYSTALLISATION TECHNIQUES

2.21          SUBLIMATION TECHNIQUES - FREEZE DRYING

2.22          SOLVENT EXTRACTION

2.23          DRYING OF LIQUIDS OR OF SOLUTIONS OF ORGANIC COMPOUNDS IN ORGANIC SOLVENTS

2.24          DISTILLATION AT ATMOSPHERIC PRESSURE

2.25          STEAM DISTILLATION

2.26          FRACTIONAL DISTILLATION AT ATMOSPHERIC PRESSURE

2.27          DISTILLATION UNDER DIMINISHED PRESSURE ('VACUUM' DISTILLATION)

2.28          HIGH VACUUM DISTILLATION - MOLECULAR DISTILLATION

2.29          VACUUM PUMPS

2.30          MANOMETERS, VACUSTATS, VACUUM GAUGES AND MANOSTATS

2.31          CHROMATOGRAPHY

2.32          STORAGE OF SAMPLES

2.33          MELTING POINT - MIXED MELTING POINTS

2.34          DETERMINATION OF BOILING POINT

2.35          DETERMINATION OF MOLECULAR WEIGHT

2.36          DETERMINATION OF OPTICAL ROTATORY POWER

2.37          DETERMINATION OF REFRACTIVE INDEX

CHAPTER 3 SPECTROSCOPIC METHODS AND THE INTERPRETATION OF SPECTRA

3.1    INFRARED SPECTROSCOPY

3.2    NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY

3.3    MASS SPECTROMETRY

3.4    ULTRAVIOLET-VISIBLE SPECTROSCOPY

CHAPTER 4 SOLVENTS AND REAGENTS

4.1    THE PURIFICATION OF COMMON ORGANIC SOLVENTS

4.2    THE PREPARATION AND PURIFICATION OF REAGENTS

CHAPTER 5 ALIPHATIC COMPOUNDS

5.1    ALKANES

5.2    ALKENES

5.3    ALKYNES

5.4    ALIPHATIC ALCOHOLS

5.5    ALIPHATIC HALIDES

5.6    ALIPHATIC ETHERS

5.7    ALIPHATIC ALDEHYDES

5.8    ALIPHATIC KETONES

5.9    DICARBONYL COMPOUNDS.

5.10CARBOHYDRATES

5.11ALIPHATIC CARBOXYLIC ACIDS

5.12CARBOXYLIC ACID DERIVATIVES

5.13ALIPHATIC NITRILES

5.14SUBSTITUTED CARBOXYLIC ACIDS AND THEIR DERIVATIVES

5.15NITROALKANES

5.16ALIPHATIC AMINES

5.17ALIPHATIC SULPHUR COMPOUNDS

5.18UNSATURATED COMPOUNDS

5.19RESOLUTION OF RACEMATES

CHAPTER 6 AROMATIC COMPOUNDS

6.1    AROMATIC HYDROCARBONS

6.2    AROMATIC NITRO COMPOUNDS

6.3    AROMATIC HALOGEN COMPOUNDS

6.4    AROMATIC SULPHONIC ACIDS AND THEIR DERIVATIVES

6.5    AROMATIC AMINES

6.6    SUBSTITUTION PRODUCTS OF AROMATIC AMINES

6.7    FORMATION OF DIAZONIUM SALTS AND THEIR USES

6.8    MISCELLANEOUS AROMATIC NITROGEN COMPOUNDS

6.9    PHENOLS AND PHENYL ETHERS

6.10    AROMATIC ALDEHYDES

6.11    AROMATIC KETONES AND OUINONES

6.12    SOME REACTIONS OF AROMATIC CARBONYL COMPOUNDS

6.13    AROMATIC CARBOXYLIC ACIDS

6.14    AROMATIC CARBOXYLIC ACID DERIVATIVES

6.15    AROMATIC NITRILES

CHAPTER 7 SELECTED ALICYCLIC COMPOUNDS

7.1    INTRAMOLECULAR NUCLEOPHILIC DISPLACEMENT REACTIONS

7.2    INTRAMOLECULAR ADDITION REACTIONS OF CARBANIONS TO A CARBONYL GROUP

7.3    INSERTION REACTIONS

7.4    RING EXPANSION AND RING CONTRACTION REACTIONS

7.5    REDUCTION OF AROMATIC COMPOUNDS

7.6    CYCLOADDiTION REACTIONS

CHAPTER 8 SELECTED HETEROCYCLIC COMPOUNDS

8.1    THREE-MEMBERED HETEROCYCLES

8.2    FOUR-MEMBERED HETEROCYCLES

8.3    FIVE-MEMBERED HETEROCYCLES

8.4    SIX-MEMBERED HETEROCYCLES

CHAPTER 9 INVESTIGATION AND CHARACTERISATION OF ORGANIC COMPOUNDS 

9.1    PHYSICAL CONSTANTS

9.2    THE STUDY OF SOLUBILITY BEHAVIOUR

9.3    DETECTION OF ELEMENTS PRESENT

9.4    SPECTROSCOPIC INFORMATION

9.5    FUNCTIONAL GROUP IDENTIFICATION

9.6    PREPARATION OF DERIVATIVES

9.7    SEPARATION OF MIXTURES OF ORGANIC COMPOUNDS

CHAPTER 10 PHYSICAL CONSTANTS OF ORGANIC COMPOUNDS

APPENDICES 

1.       THE LITERATURE OF ORGANIC CHEMISTRY

2.       INFRARED CORRELATION TABLES 

3.       NUCLEAR MAGNETIC RESONANCE CORRELATION TABLES 

4.       MASS SPECTROMETRY CORRELATION TABLES 

5.       USEFUL SOLVENT CHARACTERISTICS: HAZARD SYMBOLS 

6.       COMMON SYNTHONS AND THEIR REAGENT EQUIVALENTS 

7.       SELECTION OF MANUFACTURERS AND SUPPLIERS OF LABORATORY APPARATUS, EQUIPMENT AND CHEMICALS 

Table of atomic weights

Index 

Reference data

Abbreviations.