[内容简介]

Providing new insights into the molecular and electronic processes involved in the conversion of sunlight into chemical products, Photoelectrochemical Solar Conversion Systems: Molecular and Electronic Aspects begins with an historical overview and a survey of recent developments in the electrochemistry of semiconductors and spectroscopic techniques. It then provides a comprehensive introduction to the science of conversion cells, reviews current issues and potential directions, and covers a wide range of materials from organic to inorganic cells.

Employing a tutorial organization with balanced coverage of electrochemistry and solar energy conversion, this book covers:

• The conversion of sunlight into chemical energy and different actual conversion concepts
• Electrochemical methods for the construction and characterization of electrolyte-metal-oxide-semiconductor contacts (EMOS) in the nanodimensions, the so-called nano-emitter concept, including the electrochemical formation of metal clusters of catalytic metals and the formation of passivating layers by anodization
• The fundamentals of electrocatalysis with emphasis on the hydrogen evolution reaction and the electrochemical CO₂reduction
• Classical and quantum mechanical theories of electron transfer reactions in metal-electrolyte interfaces and their relation with surface electronics
• The physicochemical characterization of the model system Si-SiO_x-metal-electrolyte by means of modern electrochemical, surface, and spectroscopic methods
• Improvements of conversion efficiency by means of optical effects, for example, the generation of surface plasmons by nano-dimensioned arrangements of optically active metals

[目录]
Principles and Systems in Light-Induced Energy Conversion
Basic Aspects of Light-Induced Generation of Fuels
Development of Energy Conversion Systems
Advanced Concepts for Sunlight Energy Conversion: From Organic Solar Cells to Artificial Photosynthesis
Inorganic Concepts
Energy and Electron Transfer Processes
References
Nano-Dimensioned Systems Based on Semiconductor-Oxide- Metal-Electrolyte Contacts
Fundamentals of Electrochemical Phase Formation
Experimental Techniques and Experiment Designs
The Electrodeposition of Selected Systems
Anodic Oxide Growth: Mechanisms, Methods, and Properties
References
Physics of Electrolyte-Metal-Oxide-Semiconductor (EMOS) Contacts in Nano-Dimensions
The Electron Transfer in Nano-Dimensioned Schottky- Contacts
Analysis of Complex Systems: The EMOS Interface
References
Electrocatalysis on Nano-Dimensioned EMOS Contacts
Fundamental Aspects of the Metal-Electrolyte Interface
The Electron Transfer at Metal-Electrolyte Interfaces: From Butler-Volmer to Quantum Mechanical Concepts
Reaction Mechanisms in Selected Systems: Hydrogen Evolution and CO2 Reduction
Development of New Electrochemical Catalysts: Future Directions
References
Electronics and Chemistry of Electrolytes-Metal-Oxide- Semiconductor Contacts
Methods: Combination of Electrochemical Techniques with Surface-Sensitive Spectroscopy
Chemical and Electronic Properties of Electrochemical Generated Interfaces on Silicon
Modulation of the Interfacial Potential in Nano-Dimensioned EMOS Contacts
References
Optical Effects: Current Approaches and Future Directions
References